Rapid cycling of reactive nitrogen in the marine boundary layer

Nitrogen oxides are essential for the formation of secondary atmospheric aerosols and of atmospheric oxidants such as ozone and the hydroxyl radical, which controls the self-cleansing capacity of the atmosphere. Nitric acid, a major oxidation product of nitrogen oxides, has traditionally been considered to be a permanent sink of nitrogen oxides1. However, model studies predict higher ratios of nitric acid to nitrogen oxides in the troposphere than are observed.